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炭化温度和时间对不同废菌棒生物炭结构性质的影响

李思苇 SarfrazRubab 杨文浩 毛艳玲 周碧青 邢世和

李思苇,Sarfraz Rubab,杨文浩,等. 炭化温度和时间对不同废菌棒生物炭结构性质的影响 [J]. 福建农业学报,2019,34(10):1211−1220. doi: 10.19303/j.issn.1008-0384.2019.10.015
引用本文: 李思苇,Sarfraz Rubab,杨文浩,等. 炭化温度和时间对不同废菌棒生物炭结构性质的影响 [J]. 福建农业学报,2019,34(10):1211−1220. doi: 10.19303/j.issn.1008-0384.2019.10.015
LI S W, Sarfraz Rubab, YANG W H, et al. Effect of Pyrolysis Temperature and Time on Structure of Biochar Made from Discarded Mushroom Stems [J]. Fujian Journal of Agricultural Sciences,2019,34(10):1211−1220. doi: 10.19303/j.issn.1008-0384.2019.10.015
Citation: LI S W, Sarfraz Rubab, YANG W H, et al. Effect of Pyrolysis Temperature and Time on Structure of Biochar Made from Discarded Mushroom Stems [J]. Fujian Journal of Agricultural Sciences,2019,34(10):1211−1220. doi: 10.19303/j.issn.1008-0384.2019.10.015

炭化温度和时间对不同废菌棒生物炭结构性质的影响

doi: 10.19303/j.issn.1008-0384.2019.10.015
基金项目: 福建省重大科技专项(2017NZ0001);福建农林大学杰出青年基金项目(XJQ201628)
详细信息
    作者简介:

    李思苇(1993−),女,硕士研究生,研究方向:农业废弃物资源化利用(E-mail:578430676@qq.com

    通讯作者:

    杨文浩(1988−),男,博士,研究方向:土壤生物化学研究(E-mail:whyang@fafu.edu.cn

  • 中图分类号: S 141.9;X 712

Effect of Pyrolysis Temperature and Time on Structure of Biochar Made from Discarded Mushroom Stems

  • 摘要:   目的  生物炭的表面性质与其表面的官能团密切相关,探讨不同制备条件对不同材料废菌棒生物炭结构特征的影响可为废菌棒的资源化有效利用提供依据。  方法  以海鲜菇、秀珍菇、银耳的废菌棒为生物质原料,采用限氧裂解法在不同温度(400、500、600、700℃)和不同时间(1.5、2.0、2.5、3.0 h)下制备生物炭,采用傅里叶红外光谱法(FTIR)对不同废菌棒生物炭结构性质进行表征。  结果  随着炭化温度的升高和炭化时间的延长,3种菌棒生物炭蛋白质中C=O、C-N、纤维素中C-O-C、脂肪烃中-CH3和-CH2基团的相对含量都随之减少;苯环中的C-H官能团相对含量随之减少,C-C官能团相对含量随之增大,且在700℃,炭化3.0 h条件下达到最大。在相同制备条件下,海鲜菇菌棒生物炭含氧官能团吸收峰峰强最强,银耳菌棒生物炭最弱;秀珍菇菌棒生物炭苯环C-C吸收峰峰强最强,银耳菌棒生物炭最弱。  结论  随着炭化温度的升高和炭化时间的延长,生物炭中的蛋白质、多糖和脂肪酸等有机物质逐渐分解,烷基基团缺失,而芳香结构逐渐形成,在700℃,炭化3.0 h条件下生物炭结构最稳定。在3种菌棒生物炭中,海鲜菇菌棒生物炭对于重金属或有机污染物的吸附能力可能最强,秀珍菇菌棒生物炭施入土壤后固碳效果可能最好。
  • 图  1  不同炭化温度下海鲜菇生物炭的FTIR图谱

    Figure  1.  FTIR spectrum of H. marmoreus biochar made under various pyrolysis temperatures

    图  2  不同炭化温度下秀珍菇生物炭的FTIR图谱

    Figure  2.  FTIR spectrum of P. geesteranus biochar made under various pyrolysis temperatures

    图  3  不同炭化温度下银耳生物炭的FTIR图谱

    Figure  3.  FTIR spectrum of T . fuciformis biochar made under various pyrolysis temperatures

    表  1  不同炭化温度和时间下海鲜菇生物炭吸收峰的相对强度

    Table  1.   Relative intensity of absorption peak of H. marmoreus biochar made under various pyrolysis temperatures and times

    温度
    Temperature /℃
    时间
    Time /h
    吸收峰相对强度 Absorption peak relative intensity
    3 737 cm−13 433 cm−11 691 cm−11 635 cm−11 558 cm−11 458 cm−11 425 cm−11 388 cm−11 317 cm−11 040 cm−1875 cm−1785 cm−1671 cm−1
    400 1.5 0.027 0.047 0.013 0.052 0.025 0.023 0.024 0.031 0.028 0.023 0.038
    2.0 0.020 0.011 0.110 0.056 0.033 0.033 0.031 0.052 0.025 0.021 0.005
    2.5 0.024 0.051 0.170 0.061 0.041 0.038 0.037 0.067 0.041 0.031 0.038
    3.0 0.012 0.051 0.179 0.063 0.041 0.038 0.037 0.063 0.041 0.031 0.038
    500 1.5 0.012 0.014 0.011 0.043 0.014 0.007 0.004 0.024
    2.0 0.022 0.052 0.108 0.086 0.020 0.039 0.013 0.017 0.032
    2.5 0.010 0.047 0.063 0.061 0.023 0.031 0.008 0.008 0.024
    3.0 0.007 0.025 0.026 0.031 0.007 0.015 0.004 0.004 0.022
    600 1.5 0.014 0.039 0.023 0.053 0.023 0.007 0.002 0.025
    2.0 0.038 0.023 0.052 0.008 0.006 0.002 0.029
    2.5 0.026 0.031 0.031 0.061 0.025 0.008 0.005 0.028
    3.0 0.005 0.026 0.099 0.029 0.018 0.004 0.004
    700 1.5 0.017 0.017 0.009 0.013 0.037 0.013 0.005 0.002 0.028
    2.0 0.075 0.047 0.010 0.020 0.061 0.025 0.010 0.002 0.025
    2.5 0.021 0.046 0.014 0.024 0.059 0.019 0.008 0.002 0.028
    3.0 0.038 0.048 0.023 0.031 0.130 0.047 0.020 0.005 0.025
    下载: 导出CSV

    表  2  不同炭化温度和时间下秀珍菇生物炭吸收峰的相对强度

    Table  2.   Relative intensity of absorption peak of P. geesteranus biochar made under various pyrolysis temperatures and times

    温度
    Temperature /℃
    时间
    Time /h
    吸收峰相对强度 Absorption peak relative intensity
    3 743 cm−13 435 cm−11 691 cm−11 635 cm−11 547 cm−11 433 cm−11 319 cm−11 110 cm−11 051 cm−1875 cm−1786 cm−1673 cm−1472 cm−1
    4001.50.0170.0510.0890.0700.0370.0160.0040.0120.0080.004
    2.00.0400.0340.1120.1000.0530.0250.0140.015
    2.50.0110.0480.1540.0690.0600.0330.0060.0190.1000.009
    3.00.0580.0280.1250.1500.0410.0270.0330.0110.0090.009
    5001.50.0070.0480.0240.0210.1000.0100.0020.0030.0200.004
    2.00.0180.0390.0260.0870.0160.0150.0190.0100.0050.0030.004
    2.50.0210.0390.0660.0890.0270.0320.0470.0060.0070.0050.015
    3.00.0040.0600.0700.0700.0100.0700.1060.0120.0090.0120.034
    6001.50.0470.0340.0270.0630.0710.0060.0100.0010.0140.003
    2.00.0510.0150.0400.0400.0680.0710.0120.0120.0010.0160.004
    2.50.0190.0310.0230.0000.0380.0520.0290.0080.0010.0050.007
    3.00.1900.0640.0010.0540.0520.0990.0570.0140.0030.0040.015
    7001.50.0250.0590.0200.0320.0400.0700.0370.0120.0030.0040.01
    2.00.0130.0410.0050.0300.0320.0810.0360.0120.0020.0050.008
    2.50.0060.0320.0030.0170.0070.0790.0300.0140.0010.0010.015
    3.00.0160.0630.0020.0320.2300.0660.0300.0040.0010.150
    下载: 导出CSV

    表  3  不同炭化温度和时间下银耳生物炭吸收峰的相对强度

    Table  3.   Relative intensity of absorption peak of T . fuciformis biochar made under various pyrolysis temperatures and times

    温度
    Temperature /℃
    时间
    Time /h
    吸收峰相对强度 Absorption peak relative intensity
    3 737 cm−13 617 cm−13 433 cm−11 741 cm−11 691 cm−11 643 cm−11 540 cm−11 520 cm−11 460 cm−11 420 cm−11 100 cm−1669 cm−1598 cm−1
    4001.50.0340.0190.0110.0470.0470.0600.0350.0120.0090.008
    2.00.0390.0210.0190.0740.0780.0880.0540.0280.0060.008
    2.50.0290.0160.0130.0430.0440.0540.0290.0130.0080.006
    3.00.0450.0230.0050.0520.0520.0700.0360.0140.0120.007
    5001.50.0430.0210.0160.0670.0720.0890.0830.0490.0410.0240.0050.009
    2.00.0520.0270.0150.0600.0610.0810.0810.0400.0300.0130.0040.004
    2.50.0310.0160.0160.0420.0530.0770.0710.0470.0450.0300.0090.009
    3.00.0370.0180.0180.0600.0640.0730.0700.0430.0400.0270.0110.009
    6001.50.0210.0080.0030.0060.0160.0170.0290.0280.0120.0100.0100.0140.007
    2.00.0390.0180.0010.0150.0270.0230.0450.0470.0190.0130.0070.0120.006
    2.50.0420.0190.0030.0200.0410.0400.0600.0600.0290.0210.0120.0060.007
    3.00.0450.0240.0070.0180.0320.0280.0490.0520.0230.0160.0100.0110.007
    7001.50.0540.0270.0060.0230.0370.0310.0590.0610.0290.0200.0120.0060.008
    2.00.0460.0250.0040.0220.0340.0270.0580.0270.0270.0180.0120.0110.006
    2.50.0430.0220.0070.0190.0300.0250.0510.0500.0230.0150.0110.0130.007
    3.00.0230.0120.0100.0050.0110.0100.0270.0290.0130.0100.0140.0210.020
    下载: 导出CSV
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  • 收稿日期:  2019-06-12
  • 修回日期:  2019-08-21
  • 刊出日期:  2019-10-01

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